Publications at UCR after 9/2021
28. Samudrala, K. K..; Conley, M. P. Effects of Surface Acidity on the Structure of Organometallics Supported on Oxide Surfaces. Chem. Comm. 2023, 59, 4115–2127.
(Invited Perspective, Included in Chemical Communications HOT Articles 2023)
(Invited Perspective, Included in Chemical Communications HOT Articles 2023)
27. Gao, J.; Zhu, L.; Conley, M. P. Cationic Tantalum Hydrides Catalyze Hydrogenolysis and Alkane Metathesis Reactions of Parrafins and Polyethylene. J. Am. Chem. Soc., 2023, 145, 4964–4968.
26. Rodriguez, J.; Boudjelel, M.; Schrock, R. R.; Conley, M. P. A Tungsten Oxo Alkylidene Supported on Sulfated Ziroconium Oxide for Olefin Metathesis. Organometallics, In Press: 10.1021/acs.organomet.3c00008
(part of the Early Transition Metals in Organometallic Chemistry special issue)
(part of the Early Transition Metals in Organometallic Chemistry special issue)
25. Liu, S.; Conley, M. P.; Schrock, R. R. Synthesis of Mo(IV) para-Substituted Styrene Complexes and an Exploration of Their Conversion to 1-Pehnethylidene Complexes. Organometallics, In Press: 10.1021/acs.organomet.2c00473
(part of the Early Transition Metals in Organometallic Chemistry special issue)
(part of the Early Transition Metals in Organometallic Chemistry special issue)
24. Rodriguez, J.; Boudjelel, M.; Mueller, L. J.; Schrock, R. R.; Conley, M. P. Ring Contraction of a Tungstacyclopentane Supported on Silica: Direct Conversion of Ethylene to Propylene. J. Am. Chem. Soc. 2022, 144, 18761–18765.
23. Samudrala, K.; Huynh, W.; Dorn, R. W.; Rossini, A. J.; Conley, M. P. Formation of a Strong Heterogeneous Aluminum Lewis Acid on Silica. Angew. Chem. Int. Ed. 2022, e202205745.
22. Rodriguez, J.; Conley, M. P. A Heterogeneous Iridium Catalyst for the Hydroboration of Pyridines. Org. Lett. 2022, 24, 4680–4683.
21. Boudjelel, M.; Riedel, R.; Schrock, R. R.; Conley, M. P.; Berges, A. J.; Carta, V. Tungstacyclopentane Ring Contraction Yields Olefin Metathesis Catalysts. J. Am. Chem. Soc. 2022, 144, 10929–10942.
20. Bekyarova, E; Conley, M. P. The Coordination Chemistry of Oxide and Nanocarbon Materials. Dalton Trans. 2022, 51, 8557-8570.
(Invited Perspective)
(Invited Perspective)
19. Culver, D. B.; Corieri, J.; Lief, G.; Conley, M. P. Reactions of Triisobutylaluminum with Unbridged or Bridged Group IV Metallocene Dichlorides. Organometallics 2022, 41, 7, 892–899.
18. Gao, J.; Dorn, R. W.; Laurent, G.; Perras, F.; Rossini, A. J.; Conley, M. P. A Heterogeneous Palladium Catalyst for the Polymerization of Olefins Prepared by Halide Abstraction Using Surface R3Si+ Species. Angew. Chem. Int. Ed. 2022, e202117279
(chosen by the Editors as a Hot Paper)
(chosen by the Editors as a Hot Paper)
17. Liu, S; Boudjelel, M.; Schrock, R. R.; Conley, M. P.; Tsay, C. Interconversion of Molybdenum or Tungsten d2 Styrene Complexes with d0 1-Phenethylidene Analogues. J. Am. Chem. Soc. 2021, 143, 17209-17218.
16. Huynh, W.; Taylor, J. T.; Harman, H. H.; Conley, M. P. Solid-State 11B NMR Studies of Coinage Metal Complexes Containing a Phosphine Substituted Diboraantracene Ligand. Dalton Trans. 2021, 50, 14855 - 14863.
Publications at UCR before 9/2021:.
15. Culver, D. B.; Dorn, R. W.; Venkatesh, A.; Meeprasert, J.; Rossini, A. J.; Pidko, E. A.; Lipton, A. S.; Lief, G. R.; Conley, M. P. Active Sites in A Heterogeneous Organometallic Catalyst for the Polymerization of Ethylene. ACS Cent. Sci. 2021, 7, 1225-1231.
14. Rodriguez, J.; Conley, M. P. Ethylene Polymerization Activity of (R3P)Ni(codH)+ (cod = 1,5-cyclooctadiene) Sites Supported on Sulfated Zirconium Oxide. Inorg. Chem., 2021, 60, 6446-6449.
(Invited Forum Article for Heterogeneous Interfaces Through the Lens of Inorganic Chemistry)
(Invited Forum Article for Heterogeneous Interfaces Through the Lens of Inorganic Chemistry)
13. Witzke, R. J.; Chapovetsky, A.; Conley, M. P.; Kaphan, D. M.; Delferro, M. Non-Traditional Catalyst Supports in Surface Organometallic Chemistry. ACS Catal. 2020, 10, 11822-11840.
(Invited Perspective)
(Invited Perspective)
12. Huynh, W.; Conley, M. P. Origin of the 29Si NMR Chemical Shift in R3Si–X and Relationship to formation of Silylium (R3Si+) Ions. Dalton Trans. 2020, 49, 16453-16463.
(Invited article for the New Talent: Americas issue)
(Invited article for the New Talent: Americas issue)
11. Culver, D. B.; Huynh, W.; Tafazolian, H.; Conley, M. P. Solid-State 45Sc NMR Studies of Cp*2Sc–OR (R = CMe2CF3, CMe(CF3)2, C(CF3)3, SiPh3) and Relationship to the Structure of Cp*2Sc–sites Supported on Partially Dehydroxylated Silica. Organometallics, 2020, 39, 1112-1122.
(Invited article for Organometallic Chemistry at Various Length Scales)
(Invited article for Organometallic Chemistry at Various Length Scales)
10. Culver, D. B.; Venkatesh, A.; Huynh, W.; Rossini, A. J.; Conley, M. P. Al(OR)3 (R = C(CF3)3) Activated Silica: A Well-Defined Weakly Coordinating Surface Anion. Chemical Science, 2020, 11, 1510-1517.
9. Jones, C. G.; Asay, M.; Kim, L. J.; Kleinsasser, J. F.; Saha, A.; Fulton, T. J.; Berkley, K. R.; Cascio, D.; Malyutin, A. G.; Conley, M. P.; Stoltz, B. M.; Lavallo, L.; Rodríguez, J. A.; Nelson, H. M. Characterization of Reactive Organometallic Species via MicroED. ACS Cent. Sci. 2019, 5, 1507-1513
8. Rodriguez, J.; Culver, D. B.; Conley, M. P. Generation of Phosphonium Sites on Sulfated Zirconium Oxide: Relationship to Brønsted Acid Strength of Surface –OH Sites. J. Am. Chem. Soc. 2019, 141, 1484-1488.
7. Jothi, P. R.; Zhang, Y.; Yubuta, K.; Culver, D. B.; Conley, M. P.; Fokwa, B. P. T. Abundant Vanadium Diboride with Graphene-like Boron Layers for Hydrogen Evolution ACS Appl. Energy Mater. 2019, 2, 176-181.
6. Gordon, C. P.; Culver, D. B.; Conley, M. P.; Eisenstein, O.; Andersen, R. A.; Copéret, C. pi-Bond Character in Metal-Alkyl Compounds for C-H Activation: How, When, and Why? J. Am. Chem. Soc. 2019, 141, 648-656.
5. Culver, D. B.; Conley, M. P. Activation of C–F Bonds by Electrophilic Organosilicon Sites Supported on Sulfated Zirconia. Angew. Chem. Int. Ed. 2018, 130, 15118-15121.
4. Huynh, W.; Culver, D. B.; Tafazolian, H.; Conley, M. P. Solid-state 45Sc NMR of Cp*2Sc–X and Cp*2ScX(THF). Dalton Trans. 2018, 47, 13063 - 13071.
3. Culver, D. B.; Huynh, W.; Tafazolian, H.; Ong, T. C.; Conley, M. P. The Beta-Agostic Structure in (C5Me5)2ScCH2CH3: Solid-State NMR Studies of (C5Me5)2Sc–R (R = Me, Ph, Et). Angew. Chem. Int. Ed. 2018, 57, 9250-9253.
2. Culver, D. B.; Tafazolian, H.; Conley, M. P. A Bulky Pd(II) α-Diimine Catalyst Supported on Sulfated Zirconia for the Polymerization of Ethylene and Copolymerization of Ethylene and Methyl Acrylate. Organometallics, 2018, 1001-1006.
1. Tafazolian, H.; Culver, D. B.; Conley, M. P. A Well-Defined Ni(II) α-Diimine Catalyst Supported on Sulfated Zirconia for Polymerization Catalysis. Organometallics 2017, 36, 2385-2388.
Publications Prior to UCR:
33.) Copéret, C.; Allouche, F.; Chang,K.; Conley, M. P.; Delley, M. F.; Fedorov, A.; Moroz, I.; Mougel, V.; Pucino, M.; Searles, K.; Yamamoto, K.; Zhizhko, P. Bridging the Gap Between Industrial and Well-Defined Supported Catalysts. Angew. Chem. Int. Ed. 2017, 57, 6398-6440.
32.) Berruyer, P.; Moreno, L.; Conley, M. P.; Silvero, D. L.; Widdifield, C. M.; Siddiqi, G.; Gajan, D.; Lesage, A.; Copéret, C.; Emsley, L. Three-Dimensional Structure Determination of Surface Sites. J. Am. Chem. Soc. 2017, 139, 849 – 855.
31.) Valla, M.; Wischert, R.; Comas-Vives, A.; Conley, M. P.; Verel, R.; Copéret, C.; Sautet, P. Role of Tri-coordinate Al Sites in CH3ReO3 Olefin Metathesis Catalysts. J. Am. Chem. Soc. 2016, 138, 6774 – 6785.
30.) Conley, M. P.; Lapadula, G.; Sanders, K.; Gajan, D.; Lesage, A.; Rosal, I.; Maron, L.; Lukens, W. W.; Copéret, C.; Andersen, R. A.The Nature of Secondary Interactions at Electrophilic Metal Sites of Molecular and Silica-supported Organolutetium Complexes from Solid-State NMR Spectroscopy. J. Am. Chem. Soc. 2016, 138, 3831 – 3843.
29.) Copéret, C.; Comas-Vives, A.; Conley, M. P.; Estes, D.; Nunez-Zarur, F.; Fedorov, A.; Mougel, V.; Nagae, H.; Zhizhko, P.: Surface Organometallic and Coordination Chemistry towards Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities. Chem. Rev. 2016, 116, 323 – 421.
28.) Lapadula, G.; Conley, M. P.; Copéret, C.; Andersen, R. A.: Synthesis and Characterization of Rare Earth Siloxide Complexes, M[OSi(OtBu)3]3(L)x where L is HOSi(OtBu)3 and x=0 or 1. Organometallics, 2016, 34, 2271 – 2277.
27.) Conley, M. P.; Delley, M. F.; Nunez-Zarur, F.; Comas-Vives, A.; Copéret, C.: Heterolytic Activation of C–H Bonds on CrIII–O Surface Sites Is a Key Step in Catalytic Polymerization of Ethylene and Dehydrogenation of Propane. Inorg. Chem., 2015, 54, 5065–5078.
26.) Lapadula, G.; Trummer, D.; Conley, M.P.; Steinmann, M.: Ran, Ying-Fen; Brasselet, S.; Guyot, Y.; Maury, O.; Decurtins, S.; Liu, Shi-Xia; Copéret, C.: One-Photon Near-Infrared Sensitization of Well-Defined Yb(III) Surface Complexes for NIR-to-NIR Single Nanoparticle Imaging. Chem. Mat. 2015, 27, 2033–2039.
25.) Valla, M.; Conley, M. P.; Copéret, C.: MeReO3/Al2O3 and Me4Sn Activated Re2O7/Al2O3 Alkene Metathesis Catalysts have Similar Active Sites. Catal. Sci. Tech., 2015, 5, 1438–1442.
24.) Gajan, D.; Bornet, A.; Vuichoudb, B.; Milanib, J.; Melzic, R.; Veyre, L.; Thieuleux, C.; Conley, M. P.; Grüning, W. R.; Schwarzwälder, M.; Lesage, A.; Copéret, C.; Bodenhausen, G.; Emsley, L.; Jannin, S.: Hybrid Polarizing Solids for Pure Hyperpolarized Liquids through Dissolution Dynamic Nuclear Polarization. Proc. Nat. Acad. Sci. USA, 2014, 111, 14693–14697.
23.) Conley, M. P.; Forrest, W. P.; Mougel, V.; Copéret, C.; Schrock, R. R.: A Bulky Aryloxide Ligand Stabilizes a Heterogeneous Metathesis Catalyst. Angew. Chem. Int. Ed., 2014, 53, 14221–14224.
22.) Feng, G; Conley, M. P.; Jordan, R. F.: Differentiation between Chelate Ring Inversion and Aryl Rotation in a CF3-Substituted Phosphine-Sulfonate Palladium Methyl Complex. Organometallics, 2014, 33, 4486–4496.
21.) Filoneko, G. A.; Cosimi, E.; Lefort, L.; Conley, M. P.; Copéret, C.; Lutz, M.; Hensen, E. J. M.; Pidko, E. A.: Lutidine Derived Ru-CNC Hydrogenation Pincer Catalysts with Versatile Coordination Properties. ACS Catal. 2014, 4, 2667–2671.
20.) Delley, M. F.; Núñez-Zarur, F.; Conley, M. P.; Comas-Vives, A.; Siddiqi, G.; Norsic, S.; Monteil, V.; Safonova, O. V.; Christophe Copéret, C.: Proton Transfers Are Key Elementary Steps in Ethylene Polymerization on Isolated Chromium(III) Silicates. Proc. Nat. Acad. Sci. USA, 2014, 112, 11629-11629.
See commentary by K. Theopold, Proc. Nat. Acad. Sci. USA, 2014, 112, 11578-11579.
19.) Conley, M. P.; Rossini, A. J.; Comas Vives, A.; Valla, M.; Ouari, O.; Tordo, P.; Lesage, A.; Emsley, L.; Copéret, C.: Evidence for Surface rearrangement involving Q2-sites and strained siloxane bridges from 119Sn Surface Enhanced NMR Spectroscopy. Phys. Chem. Chem. Phys. 2014, 16, 17822-17827.
18.) Conley, M. P.; Copéret, C.; Thieuleux, C.: Mesostructured Hybrid Organic Silica Materials: Well-defined and regularly distributed supported Catalysts into the channel pores of a silica matrix. ACS Catal. 2014, 4, 1458-1469.
17.) Delley, M. F.; Conley, M. P.; Copéret, C.: Polymerization on CO-Reduced Phillips Catalyst initiates through the C-H bond activation of ethylene on Cr–O sites. Catal. Lett. 2014, 144, 805-888.
16.) Kermagoret, A.; Kerber, R. N.; Conley, M. P.; Callens, E.; Florian, P.; Massiot, D.; Copéret, C.; Delbecq, F.; Rozanska, X.; Sautet, P.: Chloroalkylaluminum supported on silica: a dinuclear aluminum surface species with bridging μ2–Cl–ligand for a highly efficient co-catalyst for the Ni-catalyzed dimerization of ethene. J. Catal. 2014, 313, 46-54.
15.) Conley, M. P.; Copéret, C.: State of the Art and Perspectives in the ‘Molecular Approach’ Towards Well-Defined Heterogeneous Catalysts. Top. Catal. 2014, 57, 843-851. (Invited Perspective)
14.) Conley, M. P.; Delley, M. F.; Siddiqui, G.; Lapadula, G.; Norsic, S.; Monteil, V.; Safonova, O. V.; Copéret, C.: Polymerization of Ethylene by Silica-Supported Dinuclear CrIII Sites through an Initiation Step Involving C-H Bond Activation. Angew. Chem. Int. Ed. 2014, 53, 1872-1876.
13.) Lapadula, G.; Bourdolle, A.; Allouche, F.; Conley, M.P.; del Rosal, I.; Maron, L.; Lukens, W. W.; Guyot, Y.; Andraud, C.; Brasselet, S.; Copéret, C.; Maury, O.; Andersen, R. A.: Near-IR Two-photon Microscopy Imaging of Nanoparticles Prepared by Controlled Functionalization of Silica with 4,4’diethylaminostyryl-2,2’bipyridine Yb(III) Surface Sites. Chem. Mat. 2014, 26, 1062-1073.
12.) Conley, M. P.; Mougel, V.; Peryshkov, D. V.; Forrest, W. F.; Gajan, D.; Lesage, A.; Emsley, L.; Copéret, C.; Schrock, R. R.: A well-defined silica-supported tungsten oxo alkylidene as a highly active alkene metathesis catalyst. J. Am. Chem. Soc. 2013, 135, 19068-19070.
11.) Filonenko, G. A.; Conley, M. P.; Copéret, C.; Lutz, M.; Hensen, E. J. M.; Pidko, E. A.: The Impact of Metal-ligand Cooperation in Hydrogenation of Carbon Dioxide Catalyzed by a Ruthenium PNP Pincer. ACS Catal. 2013, 3, 2522-2526.
10.) Gajan, D.; Schwarzwälder, M.; Conley, M. P.; Gruening, W. R.; Rossini, A. J.; Zagdoun, A.; Lelli, M.; Yulikov, M.; Jeschke, G.; Sauvée, C.; Ouari, O.; Tordo, P.; Veyre, L.; Lesage, A.; Thieuleux, C.; Emsley, L.; Copéret, C.: Solid-phase DNP Polarizing Matrices from Homogeneously Distributed Radicals in Mesostructured Hybrid Silica Materials. J. Am. Chem. Soc. 2013, 135, 15459-15466.
9.) Conley, M. P.; Drost, R. M.; Baffert, M.; Gajan, D.; Elsevier, C.; Franks, W. T.; Oschkinat, H.; Veyre, L.; Zagdoun, A.; Rossini, A.; Lelli, M.; Lesage, A.; Casano, G.; Ouari, O.; Tordo, P.; Emsley, L.; Copéret, C.; Thieuleux, C.: A Well-Defined Pd Hybrid Material for the Z-Selective Semi-hydrogenation of Alkynes Characterized at the Molecular Level by DNP SENS. Chem. Eur. J. 2013, 19, 12234-12238.
8.) Kermagoret, A.; Kerber, R. N.; Conley, M. P.; Callens, E.; Florian, P.; Massiot, D.; Copéret, C.; Delbecq, F.; Rozanska, X.; Sautet, P.: Triisobutylaluminum: Bulkier and Yet More Reactive Towards Silica Surfaces than Triethyl or Trimethylaluminum. Dalton Trans. 2013, 42, 12681-12687.
7.) Zagdoun, A.; Rossini, A. J.; Conley, M. P.; Grüning, W. R.; Schwarzwälder, M.; Lelli, M.; Franks, W. T.; Oschkinat, H.; Copéret, C.; Emsley, L.; Lesage, A.: Improved Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy through Controlled Incorporation of Deuterated Functional Groups. Angew. Chem. Int. Ed. 2013, 52, 1222-1225.
6.) Conley, M. P.; Copéret , C.: Solid-state NMR: An EYE Opener in Surface Chemistry. CHIMIA. 2012, 66, 752-758.
5.) Conley, M. P.; Valero, J.; de Mendoza, J. Guanidinium Based Receptors for Oxoanions. In Supramolecular Chemistry: From Molecules to Nanomaterials; Gale, P. A. Ed; Wiley-VCH: New York, 2012.
4.) Conley, M. P.; Jordan, R. F.: Cis/trans Isomerization of Phosphinesulfonate Palladium(II) Complexes. Angew. Chem. Int. Ed. 2011, 50, 3744-3746.
3.) Conley, M. P.; Burns, C. T.; Jordan, R. F.: Mechanism of Ethylene Oligomerization by a Cationic Palladium(II) Alkyl Complex that Contains a (3,5-Me2-pyrazolyl)2CHSi(p-tolyl)3) Ligand. Organometallics 2007, 26, 6750-6759.
2.) Sun, J.; Conley, M. P.; Zhang, L.; Kozmin, S. A.: Au- and Pt-Catalyzed Cycloisomerizations of 1,5-Enynes to Cyclohexadienes with a Broad Alkyne Scope. J. Am. Chem. Soc. 2006, 128, 9705-9710.
1.) Rubina, M.; Conley, M. P.; Gevorgyan, V.: Dramatic Acceleration of the Pd-Catalyzed [4+2] Benzannulation Reaction of Enynes and Diynes in the Presence of Lewis Acids and Bases: Expanded Scope and New Mechanistic Insights. J. Am. Chem. Soc. 2006, 128, 5818-5827.
32.) Berruyer, P.; Moreno, L.; Conley, M. P.; Silvero, D. L.; Widdifield, C. M.; Siddiqi, G.; Gajan, D.; Lesage, A.; Copéret, C.; Emsley, L. Three-Dimensional Structure Determination of Surface Sites. J. Am. Chem. Soc. 2017, 139, 849 – 855.
31.) Valla, M.; Wischert, R.; Comas-Vives, A.; Conley, M. P.; Verel, R.; Copéret, C.; Sautet, P. Role of Tri-coordinate Al Sites in CH3ReO3 Olefin Metathesis Catalysts. J. Am. Chem. Soc. 2016, 138, 6774 – 6785.
30.) Conley, M. P.; Lapadula, G.; Sanders, K.; Gajan, D.; Lesage, A.; Rosal, I.; Maron, L.; Lukens, W. W.; Copéret, C.; Andersen, R. A.The Nature of Secondary Interactions at Electrophilic Metal Sites of Molecular and Silica-supported Organolutetium Complexes from Solid-State NMR Spectroscopy. J. Am. Chem. Soc. 2016, 138, 3831 – 3843.
29.) Copéret, C.; Comas-Vives, A.; Conley, M. P.; Estes, D.; Nunez-Zarur, F.; Fedorov, A.; Mougel, V.; Nagae, H.; Zhizhko, P.: Surface Organometallic and Coordination Chemistry towards Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities. Chem. Rev. 2016, 116, 323 – 421.
28.) Lapadula, G.; Conley, M. P.; Copéret, C.; Andersen, R. A.: Synthesis and Characterization of Rare Earth Siloxide Complexes, M[OSi(OtBu)3]3(L)x where L is HOSi(OtBu)3 and x=0 or 1. Organometallics, 2016, 34, 2271 – 2277.
27.) Conley, M. P.; Delley, M. F.; Nunez-Zarur, F.; Comas-Vives, A.; Copéret, C.: Heterolytic Activation of C–H Bonds on CrIII–O Surface Sites Is a Key Step in Catalytic Polymerization of Ethylene and Dehydrogenation of Propane. Inorg. Chem., 2015, 54, 5065–5078.
26.) Lapadula, G.; Trummer, D.; Conley, M.P.; Steinmann, M.: Ran, Ying-Fen; Brasselet, S.; Guyot, Y.; Maury, O.; Decurtins, S.; Liu, Shi-Xia; Copéret, C.: One-Photon Near-Infrared Sensitization of Well-Defined Yb(III) Surface Complexes for NIR-to-NIR Single Nanoparticle Imaging. Chem. Mat. 2015, 27, 2033–2039.
25.) Valla, M.; Conley, M. P.; Copéret, C.: MeReO3/Al2O3 and Me4Sn Activated Re2O7/Al2O3 Alkene Metathesis Catalysts have Similar Active Sites. Catal. Sci. Tech., 2015, 5, 1438–1442.
24.) Gajan, D.; Bornet, A.; Vuichoudb, B.; Milanib, J.; Melzic, R.; Veyre, L.; Thieuleux, C.; Conley, M. P.; Grüning, W. R.; Schwarzwälder, M.; Lesage, A.; Copéret, C.; Bodenhausen, G.; Emsley, L.; Jannin, S.: Hybrid Polarizing Solids for Pure Hyperpolarized Liquids through Dissolution Dynamic Nuclear Polarization. Proc. Nat. Acad. Sci. USA, 2014, 111, 14693–14697.
23.) Conley, M. P.; Forrest, W. P.; Mougel, V.; Copéret, C.; Schrock, R. R.: A Bulky Aryloxide Ligand Stabilizes a Heterogeneous Metathesis Catalyst. Angew. Chem. Int. Ed., 2014, 53, 14221–14224.
22.) Feng, G; Conley, M. P.; Jordan, R. F.: Differentiation between Chelate Ring Inversion and Aryl Rotation in a CF3-Substituted Phosphine-Sulfonate Palladium Methyl Complex. Organometallics, 2014, 33, 4486–4496.
21.) Filoneko, G. A.; Cosimi, E.; Lefort, L.; Conley, M. P.; Copéret, C.; Lutz, M.; Hensen, E. J. M.; Pidko, E. A.: Lutidine Derived Ru-CNC Hydrogenation Pincer Catalysts with Versatile Coordination Properties. ACS Catal. 2014, 4, 2667–2671.
20.) Delley, M. F.; Núñez-Zarur, F.; Conley, M. P.; Comas-Vives, A.; Siddiqi, G.; Norsic, S.; Monteil, V.; Safonova, O. V.; Christophe Copéret, C.: Proton Transfers Are Key Elementary Steps in Ethylene Polymerization on Isolated Chromium(III) Silicates. Proc. Nat. Acad. Sci. USA, 2014, 112, 11629-11629.
See commentary by K. Theopold, Proc. Nat. Acad. Sci. USA, 2014, 112, 11578-11579.
19.) Conley, M. P.; Rossini, A. J.; Comas Vives, A.; Valla, M.; Ouari, O.; Tordo, P.; Lesage, A.; Emsley, L.; Copéret, C.: Evidence for Surface rearrangement involving Q2-sites and strained siloxane bridges from 119Sn Surface Enhanced NMR Spectroscopy. Phys. Chem. Chem. Phys. 2014, 16, 17822-17827.
18.) Conley, M. P.; Copéret, C.; Thieuleux, C.: Mesostructured Hybrid Organic Silica Materials: Well-defined and regularly distributed supported Catalysts into the channel pores of a silica matrix. ACS Catal. 2014, 4, 1458-1469.
17.) Delley, M. F.; Conley, M. P.; Copéret, C.: Polymerization on CO-Reduced Phillips Catalyst initiates through the C-H bond activation of ethylene on Cr–O sites. Catal. Lett. 2014, 144, 805-888.
16.) Kermagoret, A.; Kerber, R. N.; Conley, M. P.; Callens, E.; Florian, P.; Massiot, D.; Copéret, C.; Delbecq, F.; Rozanska, X.; Sautet, P.: Chloroalkylaluminum supported on silica: a dinuclear aluminum surface species with bridging μ2–Cl–ligand for a highly efficient co-catalyst for the Ni-catalyzed dimerization of ethene. J. Catal. 2014, 313, 46-54.
15.) Conley, M. P.; Copéret, C.: State of the Art and Perspectives in the ‘Molecular Approach’ Towards Well-Defined Heterogeneous Catalysts. Top. Catal. 2014, 57, 843-851. (Invited Perspective)
14.) Conley, M. P.; Delley, M. F.; Siddiqui, G.; Lapadula, G.; Norsic, S.; Monteil, V.; Safonova, O. V.; Copéret, C.: Polymerization of Ethylene by Silica-Supported Dinuclear CrIII Sites through an Initiation Step Involving C-H Bond Activation. Angew. Chem. Int. Ed. 2014, 53, 1872-1876.
13.) Lapadula, G.; Bourdolle, A.; Allouche, F.; Conley, M.P.; del Rosal, I.; Maron, L.; Lukens, W. W.; Guyot, Y.; Andraud, C.; Brasselet, S.; Copéret, C.; Maury, O.; Andersen, R. A.: Near-IR Two-photon Microscopy Imaging of Nanoparticles Prepared by Controlled Functionalization of Silica with 4,4’diethylaminostyryl-2,2’bipyridine Yb(III) Surface Sites. Chem. Mat. 2014, 26, 1062-1073.
12.) Conley, M. P.; Mougel, V.; Peryshkov, D. V.; Forrest, W. F.; Gajan, D.; Lesage, A.; Emsley, L.; Copéret, C.; Schrock, R. R.: A well-defined silica-supported tungsten oxo alkylidene as a highly active alkene metathesis catalyst. J. Am. Chem. Soc. 2013, 135, 19068-19070.
11.) Filonenko, G. A.; Conley, M. P.; Copéret, C.; Lutz, M.; Hensen, E. J. M.; Pidko, E. A.: The Impact of Metal-ligand Cooperation in Hydrogenation of Carbon Dioxide Catalyzed by a Ruthenium PNP Pincer. ACS Catal. 2013, 3, 2522-2526.
10.) Gajan, D.; Schwarzwälder, M.; Conley, M. P.; Gruening, W. R.; Rossini, A. J.; Zagdoun, A.; Lelli, M.; Yulikov, M.; Jeschke, G.; Sauvée, C.; Ouari, O.; Tordo, P.; Veyre, L.; Lesage, A.; Thieuleux, C.; Emsley, L.; Copéret, C.: Solid-phase DNP Polarizing Matrices from Homogeneously Distributed Radicals in Mesostructured Hybrid Silica Materials. J. Am. Chem. Soc. 2013, 135, 15459-15466.
9.) Conley, M. P.; Drost, R. M.; Baffert, M.; Gajan, D.; Elsevier, C.; Franks, W. T.; Oschkinat, H.; Veyre, L.; Zagdoun, A.; Rossini, A.; Lelli, M.; Lesage, A.; Casano, G.; Ouari, O.; Tordo, P.; Emsley, L.; Copéret, C.; Thieuleux, C.: A Well-Defined Pd Hybrid Material for the Z-Selective Semi-hydrogenation of Alkynes Characterized at the Molecular Level by DNP SENS. Chem. Eur. J. 2013, 19, 12234-12238.
8.) Kermagoret, A.; Kerber, R. N.; Conley, M. P.; Callens, E.; Florian, P.; Massiot, D.; Copéret, C.; Delbecq, F.; Rozanska, X.; Sautet, P.: Triisobutylaluminum: Bulkier and Yet More Reactive Towards Silica Surfaces than Triethyl or Trimethylaluminum. Dalton Trans. 2013, 42, 12681-12687.
7.) Zagdoun, A.; Rossini, A. J.; Conley, M. P.; Grüning, W. R.; Schwarzwälder, M.; Lelli, M.; Franks, W. T.; Oschkinat, H.; Copéret, C.; Emsley, L.; Lesage, A.: Improved Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy through Controlled Incorporation of Deuterated Functional Groups. Angew. Chem. Int. Ed. 2013, 52, 1222-1225.
6.) Conley, M. P.; Copéret , C.: Solid-state NMR: An EYE Opener in Surface Chemistry. CHIMIA. 2012, 66, 752-758.
5.) Conley, M. P.; Valero, J.; de Mendoza, J. Guanidinium Based Receptors for Oxoanions. In Supramolecular Chemistry: From Molecules to Nanomaterials; Gale, P. A. Ed; Wiley-VCH: New York, 2012.
4.) Conley, M. P.; Jordan, R. F.: Cis/trans Isomerization of Phosphinesulfonate Palladium(II) Complexes. Angew. Chem. Int. Ed. 2011, 50, 3744-3746.
3.) Conley, M. P.; Burns, C. T.; Jordan, R. F.: Mechanism of Ethylene Oligomerization by a Cationic Palladium(II) Alkyl Complex that Contains a (3,5-Me2-pyrazolyl)2CHSi(p-tolyl)3) Ligand. Organometallics 2007, 26, 6750-6759.
2.) Sun, J.; Conley, M. P.; Zhang, L.; Kozmin, S. A.: Au- and Pt-Catalyzed Cycloisomerizations of 1,5-Enynes to Cyclohexadienes with a Broad Alkyne Scope. J. Am. Chem. Soc. 2006, 128, 9705-9710.
1.) Rubina, M.; Conley, M. P.; Gevorgyan, V.: Dramatic Acceleration of the Pd-Catalyzed [4+2] Benzannulation Reaction of Enynes and Diynes in the Presence of Lewis Acids and Bases: Expanded Scope and New Mechanistic Insights. J. Am. Chem. Soc. 2006, 128, 5818-5827.